Stack Overflow has a fairly strict standard for on topic questions. Do those standards apply to this Team?
Not necessarily. This is your Team and your space to use however you see fit. So you can feel more free to ask:
- about a problem when you don't yet know all the details needed for a solution,
- questions that could be asked on the public site, but might be tailored for your organization,
- open-ended or resource recommendation questions, or even
- non-programming questions relevant to your Team.
If you see a question asked over and over, that's an ideal time to post the question (and, ideally, an answer) here. That way, you can share a link instead of composing a new answer each time. When new people join your organization, they are likely to have questions about how to get started. This is a great place to keep that sort of documentation so that anyone can edit or improve it. It's also an ideal way to document a process for your own reference in the future.
It can even be helpful to ask questions about the site, like this one!
No matter what you ask, remember that the best questions are clear and specific.